{"product_id":"eta2-complexes-of-group-10-magnus-r-buchner-9783832528478","title":"Eta2 Complexes of Group 10 with Cinnamic Acid Derivatives; Spectroscopic Properties, Stability, Reactivity and Application Potential as Photo-Switchab","description":"Homogeneous catalysts based on transition metals are of high industrial relevance. An important goal for this purpose is the light-induced start of the catalytic reaction. The electronic and steric influence of the olefin ligand upon the spectroscopic properties, stability and reactivity of bistriphenylphosphine-cinnamate and related complexes of group 10 were studied in this thesis. By means of these findings a direct prediction of the reactivity was possible based on the NMR-spectroscopic behaviour. Thus a specific design of photo-switchable complexes was possible, in which the olefin ligand could be cleaved from the metal via a selective light-induced intra-ligand cyclisation. This ring closure was examined with the ligand itself as well as in the complexes, concerning electronic and steric influences.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eAuthor:\u003c\/b\u003e Magnus R. Buchner\u003cbr\u003e\u003cb\u003eISBN-10:\u003c\/b\u003e 3832528474\u003cbr\u003e\u003cb\u003eISBN-13:\u003c\/b\u003e 9783832528478\u003cbr\u003e\u003cb\u003ePublisher:\u003c\/b\u003e Logos Verlag Berlin\u003cbr\u003e\u003cb\u003eLanguage:\u003c\/b\u003e English\u003cbr\u003e\u003cb\u003ePublished:\u003c\/b\u003e 05\/12\/2011\u003cbr\u003e\u003cb\u003ePages:\u003c\/b\u003e 629\u003cbr\u003e\u003cb\u003eFormat:\u003c\/b\u003e Paperback","brand":"Magnus R. Buchner","offers":[{"title":"Paperback","offer_id":48450124972287,"sku":"9783832528478","price":103.0,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0662\/2982\/9887\/files\/img_43bfaea2-e459-4acc-b2b5-39e97cdf3f61.jpg?v=1777266317","url":"https:\/\/www.whiterainbookhouse.com\/products\/eta2-complexes-of-group-10-magnus-r-buchner-9783832528478","provider":"WR Book House","version":"1.0","type":"link"}