{"product_id":"investigation-on-the-thermal-decomposition-chen-xu-9783832522742","title":"Investigation on the Thermal Decomposition of Cyclic Hydrocarbons with the Shock Tube Technique","description":"The reactions involving aromatic hydrocarbons play a crucial role in the combustion chemistry for the formation and growth of polyaromatic hydrocarbons (PAHs). In this work, the thermal decomposition of the single ring aromatics benzene, phenyl and ortho-benzyne have been investigated behind reflected shock waves by using a sensitive detection technique - Atomic Resonance Absorption Spectroscopy (ARAS). The unimolecular decomposition of ortho-benzyne was investigated behind reflected shock waves by taking 1,2-diiodobenzene as the thermal source. The initial concentration of ortho-benzyne was determined in situ with I-ARAS. Simultaneously, the progress of reaction was monitored by measuring the produced H atoms with H-ARAS. By reproducing the experimental H atom concentration time profiles, a two channel decomposition model of ortho-benzyne was developed. By investigating the thermal decomposition of phenyl and benzene, a complete detailed chemical reaction model was elaborated which is able to capture the measured H atom concentration profiles over the whole investigated parameter range. Thus, the present work may contribute to a better understanding and describing of high temperature combustion of aromates which are considered as major soot precursors.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eAuthor:\u003c\/b\u003e Chen Xu\u003cbr\u003e\u003cb\u003eISBN-10:\u003c\/b\u003e 3832522743\u003cbr\u003e\u003cb\u003eISBN-13:\u003c\/b\u003e 9783832522742\u003cbr\u003e\u003cb\u003ePublisher:\u003c\/b\u003e Logos Verlag Berlin\u003cbr\u003e\u003cb\u003eLanguage:\u003c\/b\u003e English\u003cbr\u003e\u003cb\u003ePublished:\u003c\/b\u003e 10\/29\/2009\u003cbr\u003e\u003cb\u003ePages:\u003c\/b\u003e 115\u003cbr\u003e\u003cb\u003eFormat:\u003c\/b\u003e Paperback","brand":"Chen Xu","offers":[{"title":"Paperback","offer_id":48450119762175,"sku":"9783832522742","price":50.0,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0662\/2982\/9887\/files\/img_a50b5d59-8c1e-4e4c-a5dc-bd33a6fb8f0f.jpg?v=1777266299","url":"https:\/\/www.whiterainbookhouse.com\/products\/investigation-on-the-thermal-decomposition-chen-xu-9783832522742","provider":"WR Book House","version":"1.0","type":"link"}