{"product_id":"macromonomers-as-a-synthetic-tool-anna-marie-zorn-9783832531973","title":"Macromonomers as a Synthetic Tool for the Construction of Complex Polymer Architectures","description":"Free radical polymerization (FRP) may be adopted to obtain macromolecules with high vinyl end-group fidelity - so-called macromonomers. The occurrence of mid-chain radicals (MCRs) in the FRP of acrylates provides the basis for the facile one-pot - one-step auto-initiated high-temperature polymerization method. The obtained macromonomers with their unsaturated terminus represent versatile synthetic building blocks for constructing polymeric architectures. A macromonomer library was synthesized based on various acrylates and its potential use in further free radical copolymerization and end-group transformation was investigated. The obtained complex polymeric materials were fully characterized via state-of-the-art polymer characterization methods, including electrospray ionization mass spectrometry (ESI-MS) hyphenated with size-exclusion chromatography (SEC\/ESI-MS) and liquid chromatography at critical conditions (LCCC).\u003cbr\u003e\u003cbr\u003e\u003cb\u003eAuthor:\u003c\/b\u003e Anna-Marie Zorn\u003cbr\u003e\u003cb\u003eISBN-10:\u003c\/b\u003e 3832531971\u003cbr\u003e\u003cb\u003eISBN-13:\u003c\/b\u003e 9783832531973\u003cbr\u003e\u003cb\u003ePublisher:\u003c\/b\u003e Logos Verlag Berlin\u003cbr\u003e\u003cb\u003eLanguage:\u003c\/b\u003e English\u003cbr\u003e\u003cb\u003ePublished:\u003c\/b\u003e 08\/03\/2012\u003cbr\u003e\u003cb\u003ePages:\u003c\/b\u003e 213\u003cbr\u003e\u003cb\u003eFormat:\u003c\/b\u003e Paperback","brand":"Anna-Marie Zorn","offers":[{"title":"Paperback","offer_id":48447569166591,"sku":"9783832531973","price":60.0,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0662\/2982\/9887\/files\/img_0c8783aa-e37d-4b08-8358-5d193261a307.jpg?v=1777233562","url":"https:\/\/www.whiterainbookhouse.com\/products\/macromonomers-as-a-synthetic-tool-anna-marie-zorn-9783832531973","provider":"WR Book House","version":"1.0","type":"link"}