{"product_id":"radical-brook-rearrangement-xiao-shen-9783527354634","title":"Radical Brook Rearrangement","description":"\u003cp\u003e\u003cb\u003eIn-depth monograph presenting innovative radical methodologies in the Brook rearrangement and their utility in organic synthesis\u003c\/b\u003e \u003c\/p\u003e\u003cp\u003e\u003ci\u003eRadical Brook Rearrangement\u003c\/i\u003e chronicles the evolution of radical Brook rearrangements, synthesizes recent advances in the field, and outlines future research directions. The book focuses on three key reactive intermediates--α-siloxyl radicals, siloxycarbenes, and silenes -- providing detailed analyses of their generation methods, substrate scope, mechanistic insights, and synthetic applications, along with practical experimental protocols. \u003c\/p\u003e\u003cp\u003eReaders will find insights on alkoxy radical generation, photocatalytic systems, and the selection of radical\/carbene acceptors. This book deliberately focuses on radical processes, excluding anionic pathways. \u003c\/p\u003e\u003cp\u003eWritten by a team of highly qualified researchers in the field, \u003ci\u003eRadical Brook Rearrangement\u003c\/i\u003e includes information on: \u003c\/p\u003e\u003cul\u003e \u003cli\u003eGeneration of siloxycarbenes for metal siloxycarbene reaction, with information on minooxycarbene reactions\u003c\/li\u003e \u003cli\u003eGeneration of siloxycarbenes for nucleophilic addition reaction, covering aldehydes and ketones as electrophiles and other electrophilic reagents\u003c\/li\u003e \u003cli\u003eGeneration of α-siloxy silyl radicals with (TMS)3SiOH, covering photoredox reactions and metallaphotoredox reactions with (TMS)3SiNHAd\u003c\/li\u003e \u003cli\u003eGeneration of α-siloxy radicals with α-silyl alcohol, covering metal-free, metal-catalyzed, photocatalyzed, and electrophotocatalyzed reactions\u003c\/li\u003e \u003c\/ul\u003e \u003cp\u003eContaining cutting-edge research discoveries on the subject, \u003ci\u003eRadical Brook Rearrangement\u003c\/i\u003e is an essential reference for chemists across specializations, materials scientists, and professionals in the pharmaceutical industry.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eAuthor:\u003c\/b\u003e Xiao Shen,Yunxiao Zhang,Gang Zhou\u003cbr\u003e\u003cb\u003eISBN-10:\u003c\/b\u003e 3527354638\u003cbr\u003e\u003cb\u003eISBN-13:\u003c\/b\u003e 9783527354634\u003cbr\u003e\u003cb\u003ePublisher:\u003c\/b\u003e Wiley-Vch\u003cbr\u003e\u003cb\u003eLanguage:\u003c\/b\u003e English\u003cbr\u003e\u003cb\u003ePublished:\u003c\/b\u003e 04\/20\/2026\u003cbr\u003e\u003cb\u003ePages:\u003c\/b\u003e 288\u003cbr\u003e\u003cb\u003eFormat:\u003c\/b\u003e Hardcover\u003c\/p\u003e","brand":"Xiao Shen","offers":[{"title":"Hardcover","offer_id":48520091730175,"sku":"9783527354634","price":143.0,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0662\/2982\/9887\/files\/img_abc12895-d2ab-4344-a7b7-2bea5df37f51.jpg?v=1778740692","url":"https:\/\/www.whiterainbookhouse.com\/products\/radical-brook-rearrangement-xiao-shen-9783527354634","provider":"WR Book House","version":"1.0","type":"link"}