{"product_id":"synthesis-and-application-of-22paracyclophane-christoph-zippel-9783832554125","title":"Synthesis and Application of [2.2]paracyclophane Derivatives in Catalysis and Material Science","description":"[2.2]Paracyclophane is a prevalent p-stacked, carbocyclic scaffold with a \"bent and battered\" structure. This results not only in a transannular communication but also in a chiral plane within the molecule if at least one substituent is present. These unique properties make this structure synthetically challenging but also scarcely investigated. A new method for enantio-separation based on kinetic resolution was developed, which allows the access to enantiomerically pure [2.2]paracyclophane-based building blocks. In a liquid crystal templated chemical vapor deposition process, [2.2]paracyclophanyl alcohols containing an additional central chiral element were evaluated for the self-assembly of nanofibers. Furthermore, the cyclopropanation of a-alkyl-a-diazo compounds with a [2.2]paracyclophane-based rhodium tetracarboxylate complex was investigated. Finally, the rigidity, regioselective functionalization, and transannular communication of [2.2]paracyclophane were exploited in the design of heterobimetallic Au(I)\/Ru(II) complexes for the study of metal-to-metal interactions.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eAuthor:\u003c\/b\u003e Christoph Zippel\u003cbr\u003e\u003cb\u003eISBN-10:\u003c\/b\u003e 3832554122\u003cbr\u003e\u003cb\u003eISBN-13:\u003c\/b\u003e 9783832554125\u003cbr\u003e\u003cb\u003ePublisher:\u003c\/b\u003e Logos Verlag Berlin\u003cbr\u003e\u003cb\u003eLanguage:\u003c\/b\u003e English\u003cbr\u003e\u003cb\u003ePublished:\u003c\/b\u003e 11\/30\/2021\u003cbr\u003e\u003cb\u003ePages:\u003c\/b\u003e 215\u003cbr\u003e\u003cb\u003eFormat:\u003c\/b\u003e Paperback\u003cbr\u003e\u003cb\u003eWeight:\u003c\/b\u003e 16.68lbs","brand":"Christoph Zippel","offers":[{"title":"Paperback","offer_id":48450142503167,"sku":"9783832554125","price":68.0,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0662\/2982\/9887\/files\/img_a45fa6e3-f8b4-4334-b856-e988dbb83f92.jpg?v=1777266395","url":"https:\/\/www.whiterainbookhouse.com\/products\/synthesis-and-application-of-22paracyclophane-christoph-zippel-9783832554125","provider":"WR Book House","version":"1.0","type":"link"}