{"product_id":"the-encyclopedia-of-chemical-electrode-marvin-antelman-9781461333760","title":"The Encyclopedia of Chemical Electrode Potentials","description":"This book is an attempt to compile the most comprehensive listing of chemical electrode potentials to date. In compiling this encyclopedia, many papers, articles, and publi- cations-often with contradictory data-were consulted. Of all the par- published material available, the authors found the following of ticular interest: G. Milazzo and S. Caroli, Tables of Standard Electrode Poten- tials, John Wiley and Sons, Inc. (1978). A. J. deBethune and N. A. Swendeman Loud, Standard Aque- ous Electrode Potentials and Temperature Coefficients at 25 C, Clifford A. Hempel (1964). W. Mansfield Clark, Oxidation-Reduction Potentials of - ganic Systems, The Williams and Wilkins Co. (1960). However, it was our intent also to include unpublished complex forma- tion EMF data. Furthermore, when we consulted published EMF data, we found that the compilations often paid no attention to disparate conditions and varying pressures and electrolyte concentrations. To achieve a useful compilation, we resorted to Nernst equation thermodynamic calculations to reconcile disparate data. We also uti- lized the following relationships to calculate EMF values for inclusion in our tables from association constants: In K = nFE log K = -nE(16. 9) RT As a practical example, consider the reaction 3 Ca + Nta- - 2e = Ca(Ntar We may write 2 Ca - 2e = Ca+ EO = -2. 87 2 3 Ca+ + Nta- = Ca(Ntar E, = ? 3 Ca - 2e + Nta- = Ca(Ntar E2 = ? xl xII INTRODUCTION Given log K Ca(Ntaf = 6. 41, 6. 41 = -(2)(16.\u003cbr\u003e\u003cbr\u003e\u003cb\u003eAuthor:\u003c\/b\u003e Marvin Antelman\u003cbr\u003e\u003cb\u003eISBN-10:\u003c\/b\u003e 1461333768\u003cbr\u003e\u003cb\u003eISBN-13:\u003c\/b\u003e 9781461333760\u003cbr\u003e\u003cb\u003ePublisher:\u003c\/b\u003e Springer\u003cbr\u003e\u003cb\u003eLanguage:\u003c\/b\u003e English\u003cbr\u003e\u003cb\u003ePublished:\u003c\/b\u003e 12\/07\/2011\u003cbr\u003e\u003cb\u003ePages:\u003c\/b\u003e 288\u003cbr\u003e\u003cb\u003eFormat:\u003c\/b\u003e Paperback\u003cbr\u003e\u003cb\u003eWeight:\u003c\/b\u003e 0.96lbs\u003cbr\u003e\u003cb\u003eSize:\u003c\/b\u003e 9.21h x 6.14w x 0.65d","brand":"Marvin Antelman","offers":[{"title":"Paperback","offer_id":46465505165567,"sku":"9781461333760","price":54.99,"currency_code":"USD","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0662\/2982\/9887\/files\/img_d820a5a5-eeb6-4c56-9c56-58b41773250f.jpg?v=1736346450","url":"https:\/\/www.whiterainbookhouse.com\/products\/the-encyclopedia-of-chemical-electrode-marvin-antelman-9781461333760","provider":"WR Book House","version":"1.0","type":"link"}