Homo- And Heterobimetallic Complexes in Catalysis: Cooperative Catalysis (Hardcover) (ISBN-13: 9783319341828)

Bimetallic templates to perform catalysis: the case of ethylene polymerization and hydroamination.- Functionalization of alkynes mediated by bimetallic catalysts. Nucleophilic additions, cross-coupling reactions, addition reactions, pericyclic reactions.- Dinuclear rhodium complexes in the hydroformylation reaction of alkenes.- Early-Late bimetallic complexes in functionalization reactions. Cyclopropanation of styrene (Ta-Ru), Kumada coupling of unactivated alkyl chlorides with alkyl Grignard reagents (Zr-Co), Hydrosilylation of ketones (Zr-Co, Ti-Rh, Nb-Rh).- Transmission of the electronic information through the metal-metal bond in dinuclear templates. CH activation (RuI), epoxidation of alkenes (RhII).- Hydrogenation reactions catalyzed by di-rhodium and di-iridium complexes. Alkynes, alkenes, imines.- Biomimetic complexes for the production of dihydrogen, reduction of CO2.- Synergism introduced by a second metal in catalysis. Reactivation of the catalyst; Catalytic binuclear elimination reaction. Hydroformylation, carbonylation of methanol.

Author: Philippe Kalck
ISBN-10: 3319341820
ISBN-13: 9783319341828
Publisher: Springer
Language: English
Published: 06/23/2016
Pages: 277
Format: Hardcover
Weight: 1.29lbs
Size: 9.21h x 6.14w x 0.69d