Macromonomers as a Synthetic Tool for the Construction of Complex Polymer Architectures (Paperback) (ISBN-13: 9783832531973)

Free radical polymerization (FRP) may be adopted to obtain macromolecules with high vinyl end-group fidelity - so-called macromonomers. The occurrence of mid-chain radicals (MCRs) in the FRP of acrylates provides the basis for the facile one-pot - one-step auto-initiated high-temperature polymerization method. The obtained macromonomers with their unsaturated terminus represent versatile synthetic building blocks for constructing polymeric architectures. A macromonomer library was synthesized based on various acrylates and its potential use in further free radical copolymerization and end-group transformation was investigated. The obtained complex polymeric materials were fully characterized via state-of-the-art polymer characterization methods, including electrospray ionization mass spectrometry (ESI-MS) hyphenated with size-exclusion chromatography (SEC/ESI-MS) and liquid chromatography at critical conditions (LCCC).

Author: Anna-Marie Zorn
ISBN-10: 3832531971
ISBN-13: 9783832531973
Publisher: Logos Verlag Berlin
Language: English
Published: 08/03/2012
Pages: 213
Format: Paperback