Spectroscopic Investigations of Hydrogen Bond Network Structures in Water Clusters (Paperback) (ISBN-13: 9784431546832)

Kenta Mizuse, Ph.D.

Date of Birth: February 16, 1984

Place of Birth: Niigata, Japan

Nationality: Japan

Since April 2011

Department of Photo-Molecular Science (Prof. Yasuhiro Ohshima's Lab.), Institute for Molecular Science, Japan

Assistant professor

April 2008-March 2011

The Japan Society for the Promotion of Science (JSPS) Research fellow

April 2006-March 2011

Department of Chemistry, Graduate School of Science, Tohoku University, Japan

Ph.D. student

Supervisor: Professor Asuka Fujii

Degree obtained: Ph.D. in Science

April 2002-March 2006

Department of Chemistry, Faculty of Science, Tohoku University, Japan

Undergraduate student

Supervisor: Professor Naohiko Mikami

Publications

1 Mizuse, K. & Fujii, A. Infrared Spectroscopy of Large Protonated Water Clusters H⁺(H₂O)_20-50 Cooled by Inert Gas Attachment. Chem. Phys. in press, doi:10.1016/j.chemphys.2012.07.012 (2013).

2 Mizuse, K. & Fujii, A. Tuning of the Internal Energy and Isomer Distribution in Small Protonated Water Clusters H⁺(H₂O)_4-8: An Application of the Inert Gas Messenger Technique. J. Phys. Chem. A 116, 4868-4877 (2012).

3 Mizuse, K., Suzuki, Y., Mikami, N. & Fujii, A. Solvation-Induced σ-Complex Structure Formation in the Gas Phase: A Revisit to the Infrared Spectroscopy of [C₆H₆-(CH₃OH)₂]⁺. J. Phys. Chem. A 115, 11156-11161 (2011).

4 Mizuse, K., Kuo, J.-L. & Fujii, A. Structural trends of ionized water networks: Infrared spectroscopy of water cluster radical cations(H₂O)_n⁺ (n = 3-11). Chem. Sci. 2, 868-876 (2011).

5 Mizuse, K. & Fujii, A. Structural Origin of the Antimagic Number in Protonated Water Clusters H⁺(H₂O)_n: Spectroscopic Observation of the "Missing" Water Molecule in the Outermost Hydration Shell. J. Phys. Chem. Lett. 2, 2130-2134 (2011).

6 Mizuse, K. & Fujii, A. Infrared photodissociation spectroscopy of H⁺(H₂O)₆-M_m (M = Ne, Ar, Kr, Xe, H₂, N₂, and CH₄): messenger-dependent balance between H₃O⁺ and H₅O₂⁺ core isomers. Phys. Chem. Chem. Phys. 13, 7129-7135 (2011).

7 Hamashima, T., Mizuse, K. & Fujii, A. Spectral Signatures of Four-Coordinated Sites in Water Clusters: Infrared Spectroscopy of Phenol-(H₂O)_n ( 20 n J. Phys. Chem. A 115, 620-625 (2011).

8 Mizuse, K., Mikami, N. & Fujii, A. Infrared Spectra and Hydrogen-Bonded Network Structures of Large Protonated Water Clusters H⁺(H₂O)_n (n=20-200). Angew. Chem. Int. Ed. 49, 10119-10122 (2010).

9 Mizuse, K., Hasegawa, H., Mikami, N. & Fujii, A. Infrared and Electronic Spectroscopy of Benzene-Ammonia Cluster Radical Cations [C₆H₆(NH₃)_1,2]⁺: Observation of Isolated and Microsolvated σ-Complexes+. J. Phys. Chem. A 114, 11060-11069 (2010).

10 Mizuse, K., Hamashima, T. & Fujii, A. Infrared Spectroscopy of Phenol-(H₂O)_n>10: StructuralStrains in Hydrogen Bond Networks of Neutral Water Clusters. J. Phys. Chem. A 113, 12134-12141 (2009).

11 Hasegawa, H. et al. Observation of an isolated intermediate of the nucleophilic aromatic substition reaction by infrared spectroscopy. Angew. Chem. Int. Ed. 47, 6008-6010 (2008).

12 Suhara, K., Fujii, A., Mizuse, K., Mikami, N. & Kuo, J. L. Compatibility between methanol and water in the three-dimensional cage formation of large-sized protonated methanol-water mixed clusters. J. Chem. Phys. 126, 194306 (2007).

13 Mizuse, K., Fujii, A. & Mikami, N. Long range influence of an excess proton on the architecture of the hydrogen bond network in large-sized water clusters. J. Chem. Phys. 126, 231101 (2007).

14 Mizuse, K., Fujii, A. & Mikami, N. Infrared and electronic spectroscopy of a model system for the nucleophilic substitution intermediate in the gas phase: The C-N valence bond formation in the benzene-ammonia cluster cation. J. Phys. Chem. A 110, 6387-6390 (2006).