Synthesis and Structural Characterization of Arsinoamide and its Metal Complexes (Paperback) (ISBN-13: 9783736970342)

The phosphinoamide chemistry has attracted a considerable attention owing to the structural diversity of the associated complexes. To further understand the properties of the P-N bond, Ashby synthesized the compound [(Ph2P-NPh)Li(Et2O)] through the deprotonation reaction of the corresponding aminophosphine with nBuLi. X-ray diffraction analyses indicated the presence of Li-P bonds (2.684 and 3.004 Å). In addition, the P-N bond length (1.672(2) Å) was relatively smaller than that of a single bond (mean value of 1.70).

Author: Chen Xiao
ISBN-10: 373697034X
ISBN-13: 9783736970342
Publisher: Cuvillier
Language: English
Published: 06/20/2019
Pages: 138
Format: Paperback
Weight: 0.38lbs
Size: 8.27h x 5.83w x 0.30d